Thursday, April 13, 2023

Extracting Gold from E-Waste: A Comprehensive List of Chemicals Used in the Process

 List of Chemicals Used to Extract Gold and Precious Metal from E-waste.

Chemical



Introduction:
Electronic waste, commonly referred to as e-waste, is a growing problem worldwide. With the advancement of technology, the demand for electronic devices has skyrocketed, leading to an increase in e-waste. E-waste contains a variety of valuable materials, including gold and other precious metals, that can be recovered through the use of chemicals. In this blog post, we will discuss the chemicals used to extract gold and other precious metals from e-waste.


Acids:
Acids are commonly used in the extraction of gold and other precious metals from e-waste. The two most commonly used acids are hydrochloric acid (HCl) and nitric acid (HNO3). Hydrochloric acid is typically used to dissolve base metals, while nitric acid is used to dissolve precious metals. HCl is available commercially in a 33% volume concentrate, while nitric acid is available in a 68% volume concentrate. These acids are highly corrosive and can dissolve most metals, including gold, but do not dissolve plastic or other non-metallic materials. A mixture of these two acids, known as aqua regia, is often used to dissolve gold and other metals in e-waste. Aqua regia is a 3:1 mixture of HCl and HNO3 and is capable of dissolving gold and other metals that are not soluble in either acid alone. However, aqua regia is highly corrosive and must be handled with extreme care. Proper protective equipment and ventilation must be used when handling these acids to prevent harm to human health. It is also important to properly dispose of the acidic waste produced during the extraction process to prevent harm to the environment.

Solvents:
Solvents are used to extract metals from e-waste that are not soluble in acids. The most commonly used solvent in e-waste extraction is cyanide. Cyanide is highly toxic and must be handled with extreme care. It is used to extract gold from e-waste that is not soluble in acids. Another solvent used in e-waste extraction is thiourea. Thiourea is less toxic than cyanide but is not as effective in extracting metals.

Oxidants:
Oxidants are used to dissolve metals in e-waste that are not soluble in acids or solvents. The most commonly used oxidant is chlorine. Chlorine gas is highly toxic and must be handled with extreme care. It is used to oxidize gold and other metals in e-waste. Another oxidant used in e-waste extraction is bromine. Bromine is less toxic than chlorine but is more expensive.

Other Chemicals:
In addition to acids, solvents, and oxidants, other chemicals are also used in the extraction of gold and other precious metals from e-waste. One such chemical is sodium metabisulphite (Na2S2O5), which is used as a reducing agent. Na2S2O5 is added to the gold-containing solution to reduce the gold ions to metallic gold, which can then be easily recovered. Another chemical used in the extraction process is urea (CH4N2O), which is used to neutralize the acidic action of aqua regia. Aqua regia is a mixture of hydrochloric acid and nitric acid that is highly corrosive and capable of dissolving gold and other metals. Urea is added to the aqua regia solution to neutralize the acid and to prevent the solution from becoming too hot. This helps to prevent the loss of volatile components and to ensure that the solution remains stable. Urea is also used to adjust the pH of the solution to ensure optimal conditions for metal extraction. These chemicals are often used in conjunction with acids, solvents, and oxidants to increase the efficiency of the extraction process.

Conclusion:
In conclusion, the extraction of gold and other precious metals from e-waste is a complex process that requires the use of various chemicals, including acids, solvents, oxidants, sodium metabisulphite, and urea. These chemicals are highly corrosive and toxic and must be handled with extreme care. While the extraction of precious metals from e-waste is an effective way to recover valuable materials, it is important to consider the environmental impact of the chemicals used in the process. Proper handling and disposal of these chemicals is crucial to prevent harm to the environment and human health.

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